A hydrogen gas electrode is made by dipping platinum wire in a solution of HCL of pH=10 and by passing hydrogen gas around the platinum wire at one atm pressure. The oxidation potential of electrode would be:
(a) 0.059 V
(b) 0.59 V
(c) 0.118 V
(d) 1.18 V
Answer
663.9k+ views
Hint: From pH value of solution, we can calculate the concentration of hydrogen ions in that solution. HCl dissociates completely in a solution.
Complete step-by-step answer:
HCl solution has a pH =10
So, we can calculate the concentration of hydrogen ions in the solution by taking a negative antilog of pH.
\[pH=-{{\log }_{10}}[{{H}^{+}}]\]
\[[{{H}^{+}}]={{10}^{-pH}}={{10}^{-10}}M\]
It is given that the pressure of hydrogen gas is 1 atmospheric pressure.
So the equation used is
\[{{E}_{cell}}=\dfrac{0.059}{n}\log \dfrac{{{({{P}_{{{H}_{2}}}})}^{0.5}}}{[{{H}^{+}}]}\]
Where \[{{E}_{cell}}\] is the electrode potential of the cell, \[{{P}_{{{H}_{2}}}}\]is the pressure of hydrogen gas, \[n\] is the number of moles, \[[{{H}^{+}}]\] is the concentration of \[{{H}^{+}}\].
Here, n=1 ,\[{{P}_{{{H}_{2}}}}\]=1 , \[[{{H}^{+}}]={{10}^{-pH}}={{10}^{-10}}M\]
Substituting these values in the equation, we get
\[{{E}_{cell}}=\dfrac{0.059}{1}\log \dfrac{1}{{{10}^{-10}}}=+0.59V\]
Therefore, the oxidation potential of electrodes is +0.59V. The correct option is (b).
Additional Information:
Hydrogen gas electrode is also called standard hydrogen electrode as it is used as a reference electrode based on the equilibrium between aqueous protons and electrons on one side and on hydrogen gas on the other side, in a solution saturated with hydrogen gas. It is a redox electrode abbreviated as SHE. It consists of a platinized platinum electrode which is dipped in an acidic solution (usually HCl) and pure hydrogen gas is bubbled through it. The acid solution should have an activity of \[{{H}^{+}}\] as \[1mold{{m}^{-3}}\]. There is a hydroseal which prevents oxygen interference.
Note: Oxidation potential of an electrode depends on the concentration of \[{{H}^{+}}\] and the pressure of the hydrogen gas. It also depends on the number of moles involved.
Complete step-by-step answer:
HCl solution has a pH =10
So, we can calculate the concentration of hydrogen ions in the solution by taking a negative antilog of pH.
\[pH=-{{\log }_{10}}[{{H}^{+}}]\]
\[[{{H}^{+}}]={{10}^{-pH}}={{10}^{-10}}M\]
It is given that the pressure of hydrogen gas is 1 atmospheric pressure.
So the equation used is
\[{{E}_{cell}}=\dfrac{0.059}{n}\log \dfrac{{{({{P}_{{{H}_{2}}}})}^{0.5}}}{[{{H}^{+}}]}\]
Where \[{{E}_{cell}}\] is the electrode potential of the cell, \[{{P}_{{{H}_{2}}}}\]is the pressure of hydrogen gas, \[n\] is the number of moles, \[[{{H}^{+}}]\] is the concentration of \[{{H}^{+}}\].
Here, n=1 ,\[{{P}_{{{H}_{2}}}}\]=1 , \[[{{H}^{+}}]={{10}^{-pH}}={{10}^{-10}}M\]
Substituting these values in the equation, we get
\[{{E}_{cell}}=\dfrac{0.059}{1}\log \dfrac{1}{{{10}^{-10}}}=+0.59V\]
Therefore, the oxidation potential of electrodes is +0.59V. The correct option is (b).
Additional Information:
Hydrogen gas electrode is also called standard hydrogen electrode as it is used as a reference electrode based on the equilibrium between aqueous protons and electrons on one side and on hydrogen gas on the other side, in a solution saturated with hydrogen gas. It is a redox electrode abbreviated as SHE. It consists of a platinized platinum electrode which is dipped in an acidic solution (usually HCl) and pure hydrogen gas is bubbled through it. The acid solution should have an activity of \[{{H}^{+}}\] as \[1mold{{m}^{-3}}\]. There is a hydroseal which prevents oxygen interference.
Note: Oxidation potential of an electrode depends on the concentration of \[{{H}^{+}}\] and the pressure of the hydrogen gas. It also depends on the number of moles involved.
Recently Updated Pages
Write structures of the following compounds i 2 Chloro3methylpentane class 11 chemistry CBSE

What is BLO What is the full form of BLO class 8 social science CBSE

Explain the Treaty of Vienna of 1815 class 10 social science CBSE

A Paragraph on Pollution in about 100-150 Words

XIX+XXX A 49 B 51 C 55 D 44 class 5 maths CBSE

If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Find the value of the expression given below sin 30circ class 11 maths CBSE

What do you mean by retardation What is its SI uni class 11 physics CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Difference between physical and chemical change class 11 chemistry CBSE

