Assertion:The acidic strength sequence $BM{{e}_{3}} < B{{(MeO)}_{3}}$
Reason: The acidic strength can also be explained by considering the existing back bonding.
(A) Assertion is true, Reason is true, and Reason is the correct explanation for Assertion
(B) Assertion is true, Reason is true, and Reason is not the correct explanation for Assertion
(C) Assertion is true, Reason is false
(D) Assertion is false, Reason is true
Answer
636.9k+ views
Hint: An atom in a compound has a lone pair of electrons and another atom has a vacant orbital placed adjacent to each other involving back bonding which makes the compound to be stable as this compound satisfies the octet rule. This bonding is effective only when the size of the valence shell matches.
Complete answer:
Given Assertion,
The acidic strength sequence $BM{{e}_{3}} < B{{(MeO)}_{3}}$
From the above statement, both triethyl borane and trimethoxy borane form 3 covalent bonds with boron in each compound.
Boron has 3 valence electrons and gains 3 more electrons from the covalent bonds and it has a total of 6 electrons. Because of the 6 valence electrons, both compounds do not fulfill the octet rule and boron becomes electron-deficient which acts as a Lewis acid.
So, trimethyl borane is more acidic than trimethoxy borane. i.e, $BM{{e}_{3}}>B{{(MeO)}_{3}}$
Hence, the Assertion is false.
Since triethyl borane is more acidic than trimethoxy borane due to the involvement of back-bonding of boron with oxygen.
Hence, Assertion is false, Reason is true
So, the correct answer is option C.
Note:
The back bonding of any acidic compound is inversely proportional to its acidic strength. So, in case of acidic strength, boron compounds have to know about back bonding. The compound which satisfies the octet rule in $\pi $ back bonding electrons move from the atomic orbital of the atom to ${{\pi }^{*}}$ the atomic orbital of another atom.
Complete answer:
Given Assertion,
The acidic strength sequence $BM{{e}_{3}} < B{{(MeO)}_{3}}$
From the above statement, both triethyl borane and trimethoxy borane form 3 covalent bonds with boron in each compound.
Boron has 3 valence electrons and gains 3 more electrons from the covalent bonds and it has a total of 6 electrons. Because of the 6 valence electrons, both compounds do not fulfill the octet rule and boron becomes electron-deficient which acts as a Lewis acid.
So, trimethyl borane is more acidic than trimethoxy borane. i.e, $BM{{e}_{3}}>B{{(MeO)}_{3}}$
Hence, the Assertion is false.
Since triethyl borane is more acidic than trimethoxy borane due to the involvement of back-bonding of boron with oxygen.
Hence, Assertion is false, Reason is true
So, the correct answer is option C.
Note:
The back bonding of any acidic compound is inversely proportional to its acidic strength. So, in case of acidic strength, boron compounds have to know about back bonding. The compound which satisfies the octet rule in $\pi $ back bonding electrons move from the atomic orbital of the atom to ${{\pi }^{*}}$ the atomic orbital of another atom.
Recently Updated Pages
If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

A car covers the first half distance between two places class 11 physics CBSE

The resultant of two vectors overrightarrow P and overrightarrow class 11 physics CBSE

Find the value of cos 135 class 11 maths CBSE

A mass M is held in place by an applied force F and class 11 physics CBSE

A solution of glucose in water is labelled as 10 dfracwv class 11 chemistry CBSE

Trending doubts
Find the value of the expression given below sin 30circ class 11 maths CBSE

What is the maximum height of a projectile class 11 physics CBSE

Derive an expression for maximum height and range of class 11 physics CBSE

Describe various types of epithelial tissues with the class 11 biology CBSE

Lysosomes are known as suicidal bags of cell why class 11 biology CBSE

State and derive law of conservation of momentum class 11 physics CBSE

