Explain the important aspects of resonance with reference to the ${ CO }_{ 3 }^{ 2- }$ ion.
Answer
663k+ views
Hint: Resonance: It is defined as the transfer of electrons from multiple bonds or a lone pair of electrons from an atom to another atom or to an adjacent single covalent bond.
Complete step-by-step answer:
Resonance can be defined as the phenomenon of the existence of a molecule in many structures due to the delocalization of electrons. These structures are similar in energy, bonding, and nonbonding pairs of electrons. Only the distribution of electrons is different. In other words, if a molecule or an ion can be shown by ${ 2 }$ or more structures differing only in the distribution of electrons (but are otherwise the same in terms of number of electrons, energy, bonding atoms, etc), then the phenomenon is called resonance. These different structures of the molecule are called resonating, canonical, or contributing structures and none of them truly explain all the properties of the molecule or ion.
Thus a resonance structure is nothing but an alternate way of drawing a Lewis dot structure for a compound. There are many ways to draw a Lewis dot structure for some molecules that still satisfy the rules (for instance, satisfying the octet rule on each atom & having the correct total electron count).
Now let us consider drawing different resonating structures with the help of carbonate ion ${ CO }_{ 3 }^{ 2- }$. Resonating structures of this ion are represented as follows;
Figure: Resonating structures of carbonate ion
Here the central oxygen atom is bonded to three oxygen atoms. As these atoms are chemically identical, therefore any of these atoms can carry a negative charge or can be bonded to the carbon atoms by a double bond. In other words, the negative charge can reside on any of the oxygen atoms. Thus these structures differ only in the distribution of electrons but are otherwise the same. Hence, in each resonating structure, each separate oxygen atom will be bonded by a double bond, while the remaining two oxygen atoms will possess a negative charge.
Note: The possibility to make a mistake is that the negative charge persists on one oxygen atom but the atoms are identical, so any of these atoms can carry a negative charge.
Complete step-by-step answer:
Resonance can be defined as the phenomenon of the existence of a molecule in many structures due to the delocalization of electrons. These structures are similar in energy, bonding, and nonbonding pairs of electrons. Only the distribution of electrons is different. In other words, if a molecule or an ion can be shown by ${ 2 }$ or more structures differing only in the distribution of electrons (but are otherwise the same in terms of number of electrons, energy, bonding atoms, etc), then the phenomenon is called resonance. These different structures of the molecule are called resonating, canonical, or contributing structures and none of them truly explain all the properties of the molecule or ion.
Thus a resonance structure is nothing but an alternate way of drawing a Lewis dot structure for a compound. There are many ways to draw a Lewis dot structure for some molecules that still satisfy the rules (for instance, satisfying the octet rule on each atom & having the correct total electron count).
Now let us consider drawing different resonating structures with the help of carbonate ion ${ CO }_{ 3 }^{ 2- }$. Resonating structures of this ion are represented as follows;
Figure: Resonating structures of carbonate ion
Here the central oxygen atom is bonded to three oxygen atoms. As these atoms are chemically identical, therefore any of these atoms can carry a negative charge or can be bonded to the carbon atoms by a double bond. In other words, the negative charge can reside on any of the oxygen atoms. Thus these structures differ only in the distribution of electrons but are otherwise the same. Hence, in each resonating structure, each separate oxygen atom will be bonded by a double bond, while the remaining two oxygen atoms will possess a negative charge.
Note: The possibility to make a mistake is that the negative charge persists on one oxygen atom but the atoms are identical, so any of these atoms can carry a negative charge.
Recently Updated Pages
If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

A car covers the first half distance between two places class 11 physics CBSE

The resultant of two vectors overrightarrow P and overrightarrow class 11 physics CBSE

Find the value of cos 135 class 11 maths CBSE

A mass M is held in place by an applied force F and class 11 physics CBSE

A solution of glucose in water is labelled as 10 dfracwv class 11 chemistry CBSE

Trending doubts
Find the value of the expression given below sin 30circ class 11 maths CBSE

What is the maximum height of a projectile class 11 physics CBSE

Derive an expression for maximum height and range of class 11 physics CBSE

Describe various types of epithelial tissues with the class 11 biology CBSE

Lysosomes are known as suicidal bags of cell why class 11 biology CBSE

State and derive law of conservation of momentum class 11 physics CBSE

