Identify the final product, $C{H_2} = C{H_2}\xrightarrow{{C{l_2},{H_2}O}}X\xrightarrow{{aq.KOH}}Y$
A. 2-chloroethanol
B. 2-chloromethanol
C. 1-chloroethanol
D. Ethylene glycol
Answer
641.4k+ views
Hint:As we remember that organic chemistry is full of chemical reactions, so to solve such a type of question we should remember the working of reagent whether it is a reducing agent or an oxidising agent for product formation.
Complete answer:
We should first look at the pattern of the reaction, we know that when an alkene will react with halide like $HCl,HBr,HI$ the reaction will involve an electrophilic addition of hydride ion to alkene resulting in the formation of carbocation as an intermediate, and it will then rearrange itself in the presence of hydroxide ion. In the given reaction, ethene will react in the same manner with the reagent chlorine and water or simply hypohalous acid, HOX. Chlorine as a dihalide will break the carbon-carbon double bond and water molecule will now attack one of the carbon and $HCl$ will be released producing an intermediate as represented:
Now this intermediate will react with aqueous KOH which is an alkaline so it will give its hydroxide ion and they will act as a strong nucleophile and replace the chlorine atom from the alkyl halide. This reaction will result in the formation of alcoholic molecules, here ethylene glycol. This can be represented as:
Therefore the end product formed is Ethylene glycol and the whole reaction can be depicted by:
Hence the correct answer is D. Ethylene glycol.
Note:
When KOH is present in alcoholic nature, it produces \[{C_2}{H_5}{O^ - }\] ions which acts as a stronger base when compared to $O{H^ - }$ ions. These ions abstracts the hydrogen from alkyl halides and results in alkene formation. Ethylene glycol is used as a coolant and it helps in reducing overheating of car engines in summer.
Complete answer:
We should first look at the pattern of the reaction, we know that when an alkene will react with halide like $HCl,HBr,HI$ the reaction will involve an electrophilic addition of hydride ion to alkene resulting in the formation of carbocation as an intermediate, and it will then rearrange itself in the presence of hydroxide ion. In the given reaction, ethene will react in the same manner with the reagent chlorine and water or simply hypohalous acid, HOX. Chlorine as a dihalide will break the carbon-carbon double bond and water molecule will now attack one of the carbon and $HCl$ will be released producing an intermediate as represented:
Now this intermediate will react with aqueous KOH which is an alkaline so it will give its hydroxide ion and they will act as a strong nucleophile and replace the chlorine atom from the alkyl halide. This reaction will result in the formation of alcoholic molecules, here ethylene glycol. This can be represented as:
Therefore the end product formed is Ethylene glycol and the whole reaction can be depicted by:
Hence the correct answer is D. Ethylene glycol.
Note:
When KOH is present in alcoholic nature, it produces \[{C_2}{H_5}{O^ - }\] ions which acts as a stronger base when compared to $O{H^ - }$ ions. These ions abstracts the hydrogen from alkyl halides and results in alkene formation. Ethylene glycol is used as a coolant and it helps in reducing overheating of car engines in summer.
Recently Updated Pages
Write structures of the following compounds i 2 Chloro3methylpentane class 11 chemistry CBSE

What is BLO What is the full form of BLO class 8 social science CBSE

Explain the Treaty of Vienna of 1815 class 10 social science CBSE

A Paragraph on Pollution in about 100-150 Words

XIX+XXX A 49 B 51 C 55 D 44 class 5 maths CBSE

If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Find the value of the expression given below sin 30circ class 11 maths CBSE

What do you mean by retardation What is its SI uni class 11 physics CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Difference between physical and chemical change class 11 chemistry CBSE

