What molecular structure is expected for iodine molecules according to the VSEPR model?
A.T-shaped
B. See-saw
C. Trigonal planar
D. Linear
Answer
663k+ views
Hint: We know that valence shell electron pair repulsion (VSEPR) theory is used to determine the geometry of molecules from the electron pairs surrounding the central atom.
Complete step by step answer:
First, we draw the structure of ${\rm{IC}}{{\rm{l}}_{\rm{3}}}$ molecule. We know that iodine is an element belonging to group 17 of the periodic table. Chlorine is also an element that belongs to the same group as iodine. The number of valence electrons of iodine is 7. Out of seven valence electrons, three electrons are shared with three chlorine atoms to form three ${\rm{I}} - {\rm{Cl}}$ bond and two pairs of lone pair electrons. So, the structure of ${\rm{IC}}{{\rm{l}}_{\rm{3}}}$ molecule is,
From the above Lewis structure of ${\rm{IC}}{{\rm{l}}_{\rm{3}}}$ molecule, we clearly see that the position of two lone pairs at the equatorial position in the trigonal bipyramidal geometry. The positions of lone pairs are$120^\circ $ apart, so they experience least repulsion compared to axial position. So, the shape of ${\rm{IC}}{{\rm{l}}_{\rm{3}}}$ molecule is T-shaped.
So, the correct answer is “Option A”.
Additional Information:
According to VSEPR theory, lone pair electrons repel each other more strongly than that of bond pair electrons. So, the decreasing order of repulsion is lp-lp>lp-bp>bp-bp.
So, repulsion between bond pair-bond pair is least and between lone pair-lone pair is highest.
Note:
Students might think that as Iodine has three bond pairs in ${\rm{IC}}{{\rm{l}}_{\rm{3}}}$, its molecular shape is trigonal planar. But it is not correct. The two lone pairs also impact on the shape of ${\rm{IC}}{{\rm{l}}_{\rm{3}}}$ molecule. If only three bond pairs present in a compound, then its molecular shape is trigonal planar, such as, in case of ${\rm{B}}{{\rm{H}}_{\rm{3}}}$.
Complete step by step answer:
First, we draw the structure of ${\rm{IC}}{{\rm{l}}_{\rm{3}}}$ molecule. We know that iodine is an element belonging to group 17 of the periodic table. Chlorine is also an element that belongs to the same group as iodine. The number of valence electrons of iodine is 7. Out of seven valence electrons, three electrons are shared with three chlorine atoms to form three ${\rm{I}} - {\rm{Cl}}$ bond and two pairs of lone pair electrons. So, the structure of ${\rm{IC}}{{\rm{l}}_{\rm{3}}}$ molecule is,
From the above Lewis structure of ${\rm{IC}}{{\rm{l}}_{\rm{3}}}$ molecule, we clearly see that the position of two lone pairs at the equatorial position in the trigonal bipyramidal geometry. The positions of lone pairs are$120^\circ $ apart, so they experience least repulsion compared to axial position. So, the shape of ${\rm{IC}}{{\rm{l}}_{\rm{3}}}$ molecule is T-shaped.
So, the correct answer is “Option A”.
Additional Information:
According to VSEPR theory, lone pair electrons repel each other more strongly than that of bond pair electrons. So, the decreasing order of repulsion is lp-lp>lp-bp>bp-bp.
So, repulsion between bond pair-bond pair is least and between lone pair-lone pair is highest.
Note:
Students might think that as Iodine has three bond pairs in ${\rm{IC}}{{\rm{l}}_{\rm{3}}}$, its molecular shape is trigonal planar. But it is not correct. The two lone pairs also impact on the shape of ${\rm{IC}}{{\rm{l}}_{\rm{3}}}$ molecule. If only three bond pairs present in a compound, then its molecular shape is trigonal planar, such as, in case of ${\rm{B}}{{\rm{H}}_{\rm{3}}}$.
Recently Updated Pages
Write structures of the following compounds i 2 Chloro3methylpentane class 11 chemistry CBSE

What is BLO What is the full form of BLO class 8 social science CBSE

Explain the Treaty of Vienna of 1815 class 10 social science CBSE

A Paragraph on Pollution in about 100-150 Words

XIX+XXX A 49 B 51 C 55 D 44 class 5 maths CBSE

If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Find the value of the expression given below sin 30circ class 11 maths CBSE

What do you mean by retardation What is its SI uni class 11 physics CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Difference between physical and chemical change class 11 chemistry CBSE

