What is the order of stability for
I) I-butene
II) cis-2-butene
III) trans-2-butene
A) $I$$<$$II$$<$$III$
B) $I$$>$$II$$>$$III$
C) $III$$>$$I$$>$$II$
D) $I$$>$$II$$>$$III$
Answer
636k+ views
Hint: Hyperconjugation is one of the phenomena which stabilizes the molecule.
The cis and trans butane are the geometrical isomers of butane.
Complete step by step answer:
Here in the question, the stability order of the given compounds should be compared for getting the answer.
For that we should know a phenomenon called hyperconjugation.
Hyperconjugation is the no bond resonance phenomenon in which the compound stabilizes itself by attracting the electrons from the alpha hydrogen to the nearest carbon.
Alpha hydrogen is the hydrogen of the nearest C with respect to which we speak about the phenomenon.
As the number of alpha hydrogen in the structure is more, more is the hyperconjugation structure and more stable the structure is.
- Now let’s consider the options and comment on its stability.
The options given here is - I-butene, cis-2-butene and trans-2-butene
Cis and trans butane are the isomers of butene.
Consider the structures of the three compounds.
First let’s see the structure of 1-butene,
It has only two alpha hydrogens, so only two hyperconjugations are possible for this structure. Hence the stability of this structure will be low.
Now let’s consider the structure of cis-2-butene.
Here there are six alpha hydrogens which are attached to the carbons but the methyl group is present in the same side which causes steric hindrance.And steric hindrance decreases the stability of the compound.
The last option is trans-2-butene
Here also six alpha hydrogens are present but the methyl group is present on the opposite side of the carbon, hence it stabilizes the structure.
So we can conclude that, as in 1-butene there is only two alpha hydrogen present, it will be the least stable structure. And comparing cis and trans isomers, cis will have the least stability since there is steric hindrance in the structure and trans-2-butene will be the most stable structure among the given options,
Hence the correct option is option (A). $I$$<$$II$$<$$III$
Note: The more substituted alkene will be the most stable one than the least substituted alkenes. And the least substituted alkenes are more stable than the unsubstituted or normal alkene.
Here the order of stability is, Alkene $<$ substituted alkenes.
Steric effect is another one factor that should be given consideration, while comparing the stabilities of the structure.
The cis and trans butane are the geometrical isomers of butane.
Complete step by step answer:
Here in the question, the stability order of the given compounds should be compared for getting the answer.
For that we should know a phenomenon called hyperconjugation.
Hyperconjugation is the no bond resonance phenomenon in which the compound stabilizes itself by attracting the electrons from the alpha hydrogen to the nearest carbon.
Alpha hydrogen is the hydrogen of the nearest C with respect to which we speak about the phenomenon.
As the number of alpha hydrogen in the structure is more, more is the hyperconjugation structure and more stable the structure is.
- Now let’s consider the options and comment on its stability.
The options given here is - I-butene, cis-2-butene and trans-2-butene
Cis and trans butane are the isomers of butene.
Consider the structures of the three compounds.
First let’s see the structure of 1-butene,
It has only two alpha hydrogens, so only two hyperconjugations are possible for this structure. Hence the stability of this structure will be low.
Now let’s consider the structure of cis-2-butene.
Here there are six alpha hydrogens which are attached to the carbons but the methyl group is present in the same side which causes steric hindrance.And steric hindrance decreases the stability of the compound.
The last option is trans-2-butene
Here also six alpha hydrogens are present but the methyl group is present on the opposite side of the carbon, hence it stabilizes the structure.
So we can conclude that, as in 1-butene there is only two alpha hydrogen present, it will be the least stable structure. And comparing cis and trans isomers, cis will have the least stability since there is steric hindrance in the structure and trans-2-butene will be the most stable structure among the given options,
Hence the correct option is option (A). $I$$<$$II$$<$$III$
Note: The more substituted alkene will be the most stable one than the least substituted alkenes. And the least substituted alkenes are more stable than the unsubstituted or normal alkene.
Here the order of stability is, Alkene $<$ substituted alkenes.
Steric effect is another one factor that should be given consideration, while comparing the stabilities of the structure.
Recently Updated Pages
If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

A car covers the first half distance between two places class 11 physics CBSE

The resultant of two vectors overrightarrow P and overrightarrow class 11 physics CBSE

Find the value of cos 135 class 11 maths CBSE

A mass M is held in place by an applied force F and class 11 physics CBSE

A solution of glucose in water is labelled as 10 dfracwv class 11 chemistry CBSE

Trending doubts
Find the value of the expression given below sin 30circ class 11 maths CBSE

One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Proton was discovered by A Thomson B Rutherford C Chadwick class 11 chemistry CBSE

Bond order ofO2 O2+ O2 and O22 is in order A O2 langle class 11 chemistry CBSE

