How many products are formed in the given reaction?
Answer
549k+ views
Hint: In order to solve the above reaction, we need to know about the pinacol-pinacolone rearrangement. It is the important process used for the conversion of $ 1 $ , $ 2 $ diols into carbonyl compounds.
Complete Step By Step Answer:
Let’s first completely understand about a very important process in organic chemistry which is named as pinacol-pinacolone rearrangement. It is the process used for the conversion of $ 1 $ , $ 2 $ diols into carbonyl compounds containing a carbon oxygen double bond. This rearrangement is done via $ 1 $ , $ 2 $ - migration which takes place under acyl conditions. This rearrangement involves the shift of the two adjacent atoms.
Pinacol is a compound that has two hydroxyl groups, each group is attached to a vicinal carbon atom. It appears like a white organic compound. Pinacolone is a ketone that has an odour like camphor and appears like a colourless liquid.
In the given above reaction, it indicates that it is an example of pinacol-pinacolone rearrangement. Here the number of products formed is two. The migratory aptitude of an aryl group is more than that of hydrogen atom or alkyl group. The products formed is shown below:
The first product is this:
The second product is as follows:
Note:
It must be remembered that this rearrangement process is very important in organic chemistry for the conversion of $ 1 $ , $ 2 $ diols into carbonyl compounds. This reaction was first prescribed by the German chemist William Rudolph Fittig in the year $ 1860 $ . Also, this rearrangement proceeds through the formation of an intermediate which is positively charged. The methyl group in the intermediate proceeds to migrate from one carbon atom to another.
Complete Step By Step Answer:
Let’s first completely understand about a very important process in organic chemistry which is named as pinacol-pinacolone rearrangement. It is the process used for the conversion of $ 1 $ , $ 2 $ diols into carbonyl compounds containing a carbon oxygen double bond. This rearrangement is done via $ 1 $ , $ 2 $ - migration which takes place under acyl conditions. This rearrangement involves the shift of the two adjacent atoms.
Pinacol is a compound that has two hydroxyl groups, each group is attached to a vicinal carbon atom. It appears like a white organic compound. Pinacolone is a ketone that has an odour like camphor and appears like a colourless liquid.
In the given above reaction, it indicates that it is an example of pinacol-pinacolone rearrangement. Here the number of products formed is two. The migratory aptitude of an aryl group is more than that of hydrogen atom or alkyl group. The products formed is shown below:
The first product is this:
The second product is as follows:
Note:
It must be remembered that this rearrangement process is very important in organic chemistry for the conversion of $ 1 $ , $ 2 $ diols into carbonyl compounds. This reaction was first prescribed by the German chemist William Rudolph Fittig in the year $ 1860 $ . Also, this rearrangement proceeds through the formation of an intermediate which is positively charged. The methyl group in the intermediate proceeds to migrate from one carbon atom to another.
Recently Updated Pages
If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

A car covers the first half distance between two places class 11 physics CBSE

The resultant of two vectors overrightarrow P and overrightarrow class 11 physics CBSE

Find the value of cos 135 class 11 maths CBSE

A mass M is held in place by an applied force F and class 11 physics CBSE

A solution of glucose in water is labelled as 10 dfracwv class 11 chemistry CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Find the value of the expression given below sin 30circ class 11 maths CBSE

What do you mean by retardation What is its SI uni class 11 physics CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Difference between physical and chemical change class 11 chemistry CBSE

