What is the rate determining step in an ${{\text{S}}_{\text{N}}}\text{2}$ reaction?
Answer
591k+ views
Hint: The ${{\text{S}}_{\text{N}}}\text{2}$ reaction stands for Substitution Nucleophilic Bimolecular reaction. A nucleophile attacks the substrate and leads to the simultaneous breaking and formation of bonds between the carbon-leaving group and carbon-nucleophile respectively. The rate is determined by the reaction between substrate and nucleophile.
Complete answer:
Many chemical reactions occur in more than one step and follow a particular reaction mechanism. The rate determining step in any chemical reaction is the slowest step that determines the speed or the rate at which the reaction will proceed. The rate equation of such multistep reactions involves the rate constant and concentration terms of the rate determining step.
Before discussing the rate determining step of an ${{\text{S}}_{\text{N}}}\text{2}$ reaction, let us take a brief look at its reaction mechanism.
The ${{\text{S}}_{\text{N}}}\text{2}$ reaction is a bimolecular nucleophilic substitution reaction. Now, the nucleophile is those groups that have electron-rich atoms capable of donating their electron pairs to an electrophile. The alkyl halides generally undergo an ${{\text{S}}_{\text{N}}}\text{2}$ reaction.
The nucleophile approaches the electron-deficient carbon atom (substrate) from the back. The bond formation between nucleophile and carbon takes place simultaneously with the breaking of the bond between carbon and a halogen atom.
This is known as the transition state which later on pushes out the halide ion as a leaving group and forms the required product with an inversion of geometry at the centre.
Here, the rate determining step is the step where the formation of transition state takes place, that is the interaction between the nucleophile and the organic substrate.
Note:
The ${{\text{S}}_{\text{N}}}\text{2}$ reaction is said to be a single-step process involving a single transition state formation but a transition state is a very short-lived species that cannot be observed directly. The 2 in ${{\text{S}}_{\text{N}}}\text{2}$ stands for bimolecular as the rate of the reaction depends on both the nucleophile and the substrate group.
Complete answer:
Many chemical reactions occur in more than one step and follow a particular reaction mechanism. The rate determining step in any chemical reaction is the slowest step that determines the speed or the rate at which the reaction will proceed. The rate equation of such multistep reactions involves the rate constant and concentration terms of the rate determining step.
Before discussing the rate determining step of an ${{\text{S}}_{\text{N}}}\text{2}$ reaction, let us take a brief look at its reaction mechanism.
The ${{\text{S}}_{\text{N}}}\text{2}$ reaction is a bimolecular nucleophilic substitution reaction. Now, the nucleophile is those groups that have electron-rich atoms capable of donating their electron pairs to an electrophile. The alkyl halides generally undergo an ${{\text{S}}_{\text{N}}}\text{2}$ reaction.
The nucleophile approaches the electron-deficient carbon atom (substrate) from the back. The bond formation between nucleophile and carbon takes place simultaneously with the breaking of the bond between carbon and a halogen atom.
This is known as the transition state which later on pushes out the halide ion as a leaving group and forms the required product with an inversion of geometry at the centre.
Here, the rate determining step is the step where the formation of transition state takes place, that is the interaction between the nucleophile and the organic substrate.
Note:
The ${{\text{S}}_{\text{N}}}\text{2}$ reaction is said to be a single-step process involving a single transition state formation but a transition state is a very short-lived species that cannot be observed directly. The 2 in ${{\text{S}}_{\text{N}}}\text{2}$ stands for bimolecular as the rate of the reaction depends on both the nucleophile and the substrate group.
Recently Updated Pages
Which of the following graphs shows the variation of class 12 physics CBSE

Draw a labelled diagram of the human male reproductive class 12 biology CBSE

Describe the experiment to compare the emf of two cells class 12 physics CBSE

What is standard hydrogen electrode

What is conventional current and electric current class 12 physics CBSE

2Bromopentane is treated with an alcoholic KOH solution class 12 chemistry CBSE

Trending doubts
Draw a labelled sketch of the human eye class 12 physics CBSE

Which are the Top 10 Largest Countries of the World?

A member of Simon commission later became Prime Minister class 12 social science CBSE

Draw ray diagrams each showing i myopic eye and ii class 12 physics CBSE

Give one example of a reptile that is viviparous class 12 biology CBSE

Which is the correct genotypic ratio of mendel dihybrid class 12 biology CBSE

