Study the following steps:
${\text{C}}{{\text{u}}_{\text{2}}}{\text{S}}\xrightarrow{{{\text{roast in air}}}}{\text{(X)}}\xrightarrow{{{\text{roast without air}}}}{\text{(Y)}}$
Based on the above steps identify X and Y.
Option X Y A Mixture of ${\text{Cu}}$ and ${\text{CuO}}$ Mixture of ${\text{Cu}}$ and ${\text{S}}{{\text{O}}_2}$ B Mixture of ${\text{C}}{{\text{u}}_{\text{2}}}{\text{O}}$ and ${\text{S}}{{\text{O}}_{\text{2}}}$ Mixture of ${\text{Cu}}$ and ${\text{S}}{{\text{O}}_2}$ C Mixture of ${\text{Cu}}$ and ${\text{S}}{{\text{O}}_{\text{2}}}$ Mixture of ${\text{CuO}}$ and ${\text{Cu}}$ D Mixture of ${\text{Cu}}$ and ${\text{CuO}}$ Mixture of ${\text{CuO}}$ and ${\text{Cu}}$
| Option | X | Y |
| A | Mixture of ${\text{Cu}}$ and ${\text{CuO}}$ | Mixture of ${\text{Cu}}$ and ${\text{S}}{{\text{O}}_2}$ |
| B | Mixture of ${\text{C}}{{\text{u}}_{\text{2}}}{\text{O}}$ and ${\text{S}}{{\text{O}}_{\text{2}}}$ | Mixture of ${\text{Cu}}$ and ${\text{S}}{{\text{O}}_2}$ |
| C | Mixture of ${\text{Cu}}$ and ${\text{S}}{{\text{O}}_{\text{2}}}$ | Mixture of ${\text{CuO}}$ and ${\text{Cu}}$ |
| D | Mixture of ${\text{Cu}}$ and ${\text{CuO}}$ | Mixture of ${\text{CuO}}$ and ${\text{Cu}}$ |
Answer
626.1k+ views
Hint:In the above question, \[{\text{C}}{{\text{u}}_{\text{2}}}{\text{S}}\] is roasted in air and hence we can say that oxidation roasting takes place. Then the product of the reaction will again react with remaining \[{\text{C}}{{\text{u}}_{\text{2}}}{\text{S}}\] to carry out reduction reaction.
Complete step by step answer:
In the above question, the equation given is:
${\text{C}}{{\text{u}}_{\text{2}}}{\text{S}}\xrightarrow{{{\text{roast in air}}}}{\text{(X)}}\xrightarrow{{{\text{roast without air}}}}{\text{(Y)}}$
The word roast indicates the roasting process is being carried out. Roasting is a process in which the ore of the material is either heated alone or in the presence of some substance so as to convert the impurities in its volatile form.
To find out X:
Since ${\text{C}}{{\text{u}}_{\text{2}}}{\text{S}}$ is roasted with air, it indicates the ore is heated in the presence of \[{{\text{O}}_{\text{2}}}\] to get converted into its oxides and impurities are converted into volatile form ,so that it can escape.
$C{u_2}S{\text{ + }}{{\text{O}}_2} \to {\text{ C}}{{\text{u}}_2}{\text{O + S}}{{\text{O}}_2}$
where ${\text{C}}{{\text{u}}_{\text{2}}}{\text{O}}$ is oxide form of ${\text{Cu}}$ and ${\text{S}}{{\text{O}}_{\text{2}}}$ is the volatile form of ${\text{S}}$.
By balancing the above equation, we get:
$2C{u_2}S{\text{ + 3}}{{\text{O}}_2} \to {\text{ 2C}}{{\text{u}}_2}{\text{O + 2S}}{{\text{O}}_2}$
To find out Y:
Roasting without air indicates that it is a reduction reaction. Here, the product ${\text{C}}{{\text{u}}_{\text{2}}}{\text{O}}$ reacts with remaining ${\text{C}}{{\text{u}}_{\text{2}}}{\text{S}}$.
${\text{C}}{{\text{u}}_{\text{2}}}{\text{S + C}}{{\text{u}}_{\text{2}}}{\text{O }} \to {\text{ Cu + S}}{{\text{O}}_{\text{2}}}$
By balancing the above equation, we get:
${\text{2C}}{{\text{u}}_{\text{2}}}{\text{S + C}}{{\text{u}}_{\text{2}}}{\text{O }} \to {\text{ 6Cu + S}}{{\text{O}}_{\text{2}}}$
As here the product reacts with its reactant and gets reduced therefore, this is a self-reduction reaction.
As X is a mixture of ${\text{C}}{{\text{u}}_{\text{2}}}{\text{O}}$ and ${\text{S}}{{\text{O}}_2}$, Y is a mixture of ${\text{Cu}}$ and ${\text{S}}{{\text{O}}_{\text{2}}}$.
Therefore, option B is correct.
Note:
We need to remember that not all metals are capable of undergoing self-reduction processes. Only the less electropositive metals like Hg, Pb, Cu etc. can take part.
The sulphide ores of the electropositive metals like Hg, Pb, Cu etc. are heated in the presence of air to convert the part of the ore into the oxide or sulphate which then reacts with sulphide ore to obtain the metal and sulphur dioxide. In this process, no reducing agent is used.
Complete step by step answer:
In the above question, the equation given is:
${\text{C}}{{\text{u}}_{\text{2}}}{\text{S}}\xrightarrow{{{\text{roast in air}}}}{\text{(X)}}\xrightarrow{{{\text{roast without air}}}}{\text{(Y)}}$
The word roast indicates the roasting process is being carried out. Roasting is a process in which the ore of the material is either heated alone or in the presence of some substance so as to convert the impurities in its volatile form.
To find out X:
Since ${\text{C}}{{\text{u}}_{\text{2}}}{\text{S}}$ is roasted with air, it indicates the ore is heated in the presence of \[{{\text{O}}_{\text{2}}}\] to get converted into its oxides and impurities are converted into volatile form ,so that it can escape.
$C{u_2}S{\text{ + }}{{\text{O}}_2} \to {\text{ C}}{{\text{u}}_2}{\text{O + S}}{{\text{O}}_2}$
where ${\text{C}}{{\text{u}}_{\text{2}}}{\text{O}}$ is oxide form of ${\text{Cu}}$ and ${\text{S}}{{\text{O}}_{\text{2}}}$ is the volatile form of ${\text{S}}$.
By balancing the above equation, we get:
$2C{u_2}S{\text{ + 3}}{{\text{O}}_2} \to {\text{ 2C}}{{\text{u}}_2}{\text{O + 2S}}{{\text{O}}_2}$
To find out Y:
Roasting without air indicates that it is a reduction reaction. Here, the product ${\text{C}}{{\text{u}}_{\text{2}}}{\text{O}}$ reacts with remaining ${\text{C}}{{\text{u}}_{\text{2}}}{\text{S}}$.
${\text{C}}{{\text{u}}_{\text{2}}}{\text{S + C}}{{\text{u}}_{\text{2}}}{\text{O }} \to {\text{ Cu + S}}{{\text{O}}_{\text{2}}}$
By balancing the above equation, we get:
${\text{2C}}{{\text{u}}_{\text{2}}}{\text{S + C}}{{\text{u}}_{\text{2}}}{\text{O }} \to {\text{ 6Cu + S}}{{\text{O}}_{\text{2}}}$
As here the product reacts with its reactant and gets reduced therefore, this is a self-reduction reaction.
As X is a mixture of ${\text{C}}{{\text{u}}_{\text{2}}}{\text{O}}$ and ${\text{S}}{{\text{O}}_2}$, Y is a mixture of ${\text{Cu}}$ and ${\text{S}}{{\text{O}}_{\text{2}}}$.
Therefore, option B is correct.
Note:
We need to remember that not all metals are capable of undergoing self-reduction processes. Only the less electropositive metals like Hg, Pb, Cu etc. can take part.
The sulphide ores of the electropositive metals like Hg, Pb, Cu etc. are heated in the presence of air to convert the part of the ore into the oxide or sulphate which then reacts with sulphide ore to obtain the metal and sulphur dioxide. In this process, no reducing agent is used.
Recently Updated Pages
If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

A car covers the first half distance between two places class 11 physics CBSE

The resultant of two vectors overrightarrow P and overrightarrow class 11 physics CBSE

Find the value of cos 135 class 11 maths CBSE

A mass M is held in place by an applied force F and class 11 physics CBSE

A solution of glucose in water is labelled as 10 dfracwv class 11 chemistry CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Find the value of the expression given below sin 30circ class 11 maths CBSE

What do you mean by retardation What is its SI uni class 11 physics CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Difference between physical and chemical change class 11 chemistry CBSE

