The conversion of primary aromatic amines into diazonium salts is known as ___________.
Answer
631.5k+ views
Hint:When primary amines are treated with a cold solution of nitrous acid generated in situ by the addition of sodium nitrite to the primary amine solution, then a bright coloured dye is formed that is called a diazo dye.
Complete answer:
The process of formation of the diazo compounds is called diazotization. The reaction was first reported by Peter Griess in the year 1858 who subsequently discovered several reactions of this new set of compounds. Most commonly diazonium salts are prepared by the treating a mixture of primary aromatic amine with sodium nitrate and dilute hydrochloric acid in the temperature range ${{\left( \text{0-5} \right)}^{\text{0}}}\text{C}$ as the diazo dyes dissociate at warm temperatures.
Hence, the conversion of the primary aromatic amines into diazonium salts is known as Diazotization reaction of Diazo coupling reaction.
Note:
The diazo compounds serve as intermediates in organic reactions and different other compounds can be formed from them.
When diazonium salts are treated with dilute hypophosphorous acid, ethanol, or sodium stannite gives benzene. When diazonium salts are treated with water and then it is heated then phenols are formed. Nitrobenzene can be obtained by treating benzenediazonium fluoroborate with sodium nitrate in presence of copper nitrate. Cyano groups cannot be introduced by nucleophilic substitutions of the haloarenes but such compounds can be prepared from diazo salts using cuprous cyanide and the reaction is called “Sandmeyer Reaction''. The aryl group in the diazo salt can be introduced by its reaction with benzene in the presence of sodium hydroxide.
Complete answer:
The process of formation of the diazo compounds is called diazotization. The reaction was first reported by Peter Griess in the year 1858 who subsequently discovered several reactions of this new set of compounds. Most commonly diazonium salts are prepared by the treating a mixture of primary aromatic amine with sodium nitrate and dilute hydrochloric acid in the temperature range ${{\left( \text{0-5} \right)}^{\text{0}}}\text{C}$ as the diazo dyes dissociate at warm temperatures.
Hence, the conversion of the primary aromatic amines into diazonium salts is known as Diazotization reaction of Diazo coupling reaction.
Note:
The diazo compounds serve as intermediates in organic reactions and different other compounds can be formed from them.
When diazonium salts are treated with dilute hypophosphorous acid, ethanol, or sodium stannite gives benzene. When diazonium salts are treated with water and then it is heated then phenols are formed. Nitrobenzene can be obtained by treating benzenediazonium fluoroborate with sodium nitrate in presence of copper nitrate. Cyano groups cannot be introduced by nucleophilic substitutions of the haloarenes but such compounds can be prepared from diazo salts using cuprous cyanide and the reaction is called “Sandmeyer Reaction''. The aryl group in the diazo salt can be introduced by its reaction with benzene in the presence of sodium hydroxide.
Recently Updated Pages
Which of the following graphs shows the variation of class 12 physics CBSE

Draw a labelled diagram of the human male reproductive class 12 biology CBSE

Describe the experiment to compare the emf of two cells class 12 physics CBSE

What is standard hydrogen electrode

What is conventional current and electric current class 12 physics CBSE

2Bromopentane is treated with an alcoholic KOH solution class 12 chemistry CBSE

Trending doubts
Draw a labelled sketch of the human eye class 12 physics CBSE

Which are the Top 10 Largest Countries of the World?

Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE

Draw ray diagrams each showing i myopic eye and ii class 12 physics CBSE

Which is the correct genotypic ratio of mendel dihybrid class 12 biology CBSE

What is the Full Form of PVC, PET, HDPE, LDPE, PP and PS ?

