The IUPAC name of the following compound is 4-(ethoxycarbonyl) benzoic acid.
(A)True
(B)False
Answer
659.4k+ views
Hint: First choose the longest carbon chain to be the parent chain and then see which of the functional groups is of highest priority. Start numbering the chain from the position of most prior functional groups towards the substituent.
Complete answer:
-The first step in IUPAC nomenclature is identifying the longest carbon chain.
Here the longest chain is the 6 carbon cyclic structure benzene.
Also, in the given structure there are 2 functional groups. They are carboxylic acid and ester group out of which carboxylic acid is of highest priority and thus the major functional group.
So, the parent chain will be the benzene with carboxylic acid which is called benzoic acid.
-Now we will look at the substituent group. In this there is an ethyl group attached to the oxygen atom of the carbonyl group and so it will be known as ethoxycarbonyl.
This ethoxycarbonyl group is attached at 4th position while numbering from position of carboxylic acid. The numbering will be done as follows:
So, the IUPAC name of this structure will be 4-(ethoxycarbonyl) benzoic acid. It has a molecular formula of: ${C_{10}}{H_{10}}{O_4}$.
Hence the correct option is: (A) True.
Note:
The priority order of the functional groups is: carboxylic acid > sulfonic acid > ester > acid halide > amide > nitrile > aldehyde > ketone > alcohol > thiol > amine. If any compound has two or more functional groups the numbering is always done on the basis of the priority of the functional groups.
Complete answer:
-The first step in IUPAC nomenclature is identifying the longest carbon chain.
Here the longest chain is the 6 carbon cyclic structure benzene.
Also, in the given structure there are 2 functional groups. They are carboxylic acid and ester group out of which carboxylic acid is of highest priority and thus the major functional group.
So, the parent chain will be the benzene with carboxylic acid which is called benzoic acid.
-Now we will look at the substituent group. In this there is an ethyl group attached to the oxygen atom of the carbonyl group and so it will be known as ethoxycarbonyl.
This ethoxycarbonyl group is attached at 4th position while numbering from position of carboxylic acid. The numbering will be done as follows:
So, the IUPAC name of this structure will be 4-(ethoxycarbonyl) benzoic acid. It has a molecular formula of: ${C_{10}}{H_{10}}{O_4}$.
Hence the correct option is: (A) True.
Note:
The priority order of the functional groups is: carboxylic acid > sulfonic acid > ester > acid halide > amide > nitrile > aldehyde > ketone > alcohol > thiol > amine. If any compound has two or more functional groups the numbering is always done on the basis of the priority of the functional groups.
Recently Updated Pages
Which of the following graphs shows the variation of class 12 physics CBSE

Draw a labelled diagram of the human male reproductive class 12 biology CBSE

Describe the experiment to compare the emf of two cells class 12 physics CBSE

What is standard hydrogen electrode

What is conventional current and electric current class 12 physics CBSE

2Bromopentane is treated with an alcoholic KOH solution class 12 chemistry CBSE

Trending doubts
Draw a labelled sketch of the human eye class 12 physics CBSE

Which are the Top 10 Largest Countries of the World?

Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE

Draw ray diagrams each showing i myopic eye and ii class 12 physics CBSE

Which is the correct genotypic ratio of mendel dihybrid class 12 biology CBSE

What is the Full Form of PVC, PET, HDPE, LDPE, PP and PS ?

