Which compound is optically active?
(A) $ Butan - 1 - amine$
(B) $ Butan - 2 - amine$
(C) $ 2 - methylpropan - 1 - amine$
(D) $ 2 - methylpropan - 2 - amine$
Answer
549k+ views
Hint: The chemical compounds consisting of at least one chiral carbon is optically active. Chiral carbon is the carbon attached to the four different groups. When all the carbon atoms in the compound are attached to two or more same groups, then that compound can be known as optically inactive.
Complete answer:
The presence of chiral carbon gives optical activity to the molecule.
Option A consists of $ Butan - 1 - amine$ , in which the carbon chain consists of four carbon atoms. The amine group is at $ {1^{st}} $ position. The structure of $ Butan - 1 - amine$ will be $ C{H_3}C{H_2}C{H_2}C{H_2}N{H_2} $ . None of the carbon is chiral. So, it is not optically active.
Option B consists of $ Butan - 2 - amine$ . The structure of $ Butan - 2 - amine$ will be $ C{H_3}C{H_2}CH\left( {N{H_2}} \right)C{H_3} $ . The carbon to which an amine group is attached is chiral carbon. So, it is optically active.
Option C consists of $ 2 - methylpropan - 1 - amine$ . The structure of $ 2 - methylpropan - 1 - amine$ will be $ C{H_3}CH\left( {C{H_3}} \right)C{H_2}N{H_2} $ . None of the carbon is chiral carbon. Thus, it is optically inactive.
Option D consists of $ 2 - methylpropan - 2 - amine$ . The structure of $ 2 - methylpropan - 2 - amine$ will be $ C{H_3}C\left( {C{H_3}} \right)\left( {N{H_2}} \right)C{H_3} $ . None of the carbon is chiral carbon. Thus, it is optically inactive.
Thus, in the given compounds, $ C{H_3}C{H_2}C{H_2}C{H_2}N{H_2} $ is an optically active compound.
Option A is the correct one.
Note:
When any chemical compound is optically active, it can be classified into two forms namely d-form and l-form. These two forms rotate the plane-polarized light in different directions. d-form rotates the plane polarised light towards the right side which can be known as Dextro and the l-form rotates the plane polarised towards the left side which can be known as leavo.
Complete answer:
The presence of chiral carbon gives optical activity to the molecule.
Option A consists of $ Butan - 1 - amine$ , in which the carbon chain consists of four carbon atoms. The amine group is at $ {1^{st}} $ position. The structure of $ Butan - 1 - amine$ will be $ C{H_3}C{H_2}C{H_2}C{H_2}N{H_2} $ . None of the carbon is chiral. So, it is not optically active.
Option B consists of $ Butan - 2 - amine$ . The structure of $ Butan - 2 - amine$ will be $ C{H_3}C{H_2}CH\left( {N{H_2}} \right)C{H_3} $ . The carbon to which an amine group is attached is chiral carbon. So, it is optically active.
Option C consists of $ 2 - methylpropan - 1 - amine$ . The structure of $ 2 - methylpropan - 1 - amine$ will be $ C{H_3}CH\left( {C{H_3}} \right)C{H_2}N{H_2} $ . None of the carbon is chiral carbon. Thus, it is optically inactive.
Option D consists of $ 2 - methylpropan - 2 - amine$ . The structure of $ 2 - methylpropan - 2 - amine$ will be $ C{H_3}C\left( {C{H_3}} \right)\left( {N{H_2}} \right)C{H_3} $ . None of the carbon is chiral carbon. Thus, it is optically inactive.
Thus, in the given compounds, $ C{H_3}C{H_2}C{H_2}C{H_2}N{H_2} $ is an optically active compound.
Option A is the correct one.
Note:
When any chemical compound is optically active, it can be classified into two forms namely d-form and l-form. These two forms rotate the plane-polarized light in different directions. d-form rotates the plane polarised light towards the right side which can be known as Dextro and the l-form rotates the plane polarised towards the left side which can be known as leavo.
Recently Updated Pages
Which of the following graphs shows the variation of class 12 physics CBSE

Draw a labelled diagram of the human male reproductive class 12 biology CBSE

Describe the experiment to compare the emf of two cells class 12 physics CBSE

What is standard hydrogen electrode

What is conventional current and electric current class 12 physics CBSE

2Bromopentane is treated with an alcoholic KOH solution class 12 chemistry CBSE

Trending doubts
Draw a labelled sketch of the human eye class 12 physics CBSE

Which are the Top 10 Largest Countries of the World?

Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE

Draw ray diagrams each showing i myopic eye and ii class 12 physics CBSE

Which is the correct genotypic ratio of mendel dihybrid class 12 biology CBSE

What is the Full Form of PVC, PET, HDPE, LDPE, PP and PS ?

