Which mixture is given by Dodecane in the presence of Platinum?
Answer
558.6k+ views
Hint: The heat-induced fragmentation of a chemical in the absence of air is known as pyrolysis. It's not the same as setting fire to something. It occurs when there is no air available, preventing the oxidation of chemicals. The pyrolysis of alkanes is known as cracking. Noble metals like Platinum,palladium are used as a catalyst in the pyrolysis process.
Complete answer:
When alkane vapours pass across red-hot metal in the absence of air, they decompose into smaller, simpler hydrocarbons. Without the use of a catalyst, this process takes place at high pressures and temperatures. A catalyst, such as palladium or platinum, is required for this reaction at low pressures and temperatures. During the fractionation process, considerable amounts of hydrocarbons are usually obtained.
The hydrocarbon molecules randomly break down into smaller hydrocarbon compounds during cracking, with a few of the products containing carbon-carbon double bonds.
The following are the factors that contribute to the creation of products during cracking:
Temperature and pressure
Nature of alkane
Presence or absence of a catalyst
Alkane cracking is governed by a mechanism known as the free radical mechanism. It is very important in the petroleum sector. By cracking, the higher molecules of an alkane are converted into lower molecules (from petrol ${C_6}$ to ${C_{11}}$ ).
When dodecane (a component of kerosene oil) is heated at $973K$ under the catalytic action of palladium, nickel, or platinum, it produces a combination of pentane and heptane as pyrolysis products.
\[{{\text{C}}_{12}}{{\text{H}}_{26}}\xrightarrow{{{\text{Pt / Pd / Ni}}}}{{\text{C}}_7}{{\text{H}}_{16}} + {{\text{C}}_5}{{\text{H}}_{10}} + {\text{Other Products}}\]
Note:
Pyrolysis is the process of a chemical decomposing with the use of heat. Cracking is the pyrolysis of higher alkanes to generate a combination of lower alkanes and alkenes. It's usually done by heating the higher alkanes to high temperatures at pressures ranging from \[6 - 7{\text{ atm}}\], either with or without a catalyst. Pyrolysis of alkanes occurs through a free radical mechanism, which involves the breaking of \[{\text{C}} - {\text{H}}\] and \[{\text{C}} - {\text{C}}\] bonds.
Complete answer:
When alkane vapours pass across red-hot metal in the absence of air, they decompose into smaller, simpler hydrocarbons. Without the use of a catalyst, this process takes place at high pressures and temperatures. A catalyst, such as palladium or platinum, is required for this reaction at low pressures and temperatures. During the fractionation process, considerable amounts of hydrocarbons are usually obtained.
The hydrocarbon molecules randomly break down into smaller hydrocarbon compounds during cracking, with a few of the products containing carbon-carbon double bonds.
The following are the factors that contribute to the creation of products during cracking:
Temperature and pressure
Nature of alkane
Presence or absence of a catalyst
Alkane cracking is governed by a mechanism known as the free radical mechanism. It is very important in the petroleum sector. By cracking, the higher molecules of an alkane are converted into lower molecules (from petrol ${C_6}$ to ${C_{11}}$ ).
When dodecane (a component of kerosene oil) is heated at $973K$ under the catalytic action of palladium, nickel, or platinum, it produces a combination of pentane and heptane as pyrolysis products.
\[{{\text{C}}_{12}}{{\text{H}}_{26}}\xrightarrow{{{\text{Pt / Pd / Ni}}}}{{\text{C}}_7}{{\text{H}}_{16}} + {{\text{C}}_5}{{\text{H}}_{10}} + {\text{Other Products}}\]
Note:
Pyrolysis is the process of a chemical decomposing with the use of heat. Cracking is the pyrolysis of higher alkanes to generate a combination of lower alkanes and alkenes. It's usually done by heating the higher alkanes to high temperatures at pressures ranging from \[6 - 7{\text{ atm}}\], either with or without a catalyst. Pyrolysis of alkanes occurs through a free radical mechanism, which involves the breaking of \[{\text{C}} - {\text{H}}\] and \[{\text{C}} - {\text{C}}\] bonds.
Recently Updated Pages
Write structures of the following compounds i 2 Chloro3methylpentane class 11 chemistry CBSE

What is BLO What is the full form of BLO class 8 social science CBSE

Explain the Treaty of Vienna of 1815 class 10 social science CBSE

A Paragraph on Pollution in about 100-150 Words

XIX+XXX A 49 B 51 C 55 D 44 class 5 maths CBSE

If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Find the value of the expression given below sin 30circ class 11 maths CBSE

What do you mean by retardation What is its SI uni class 11 physics CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Difference between physical and chemical change class 11 chemistry CBSE

